Crystal engineering with multipoint halogen bonding
- The combination of singly or doubly bidentate halogen‐bond donors with double bidentate acceptors was investigated as a supramolecular synthon in crystal engineering. The crystal topologies obtained feature novel halogen‐bonding motifs like double two‐point recognition and infinite chains or networks based on two‐point interactions. Induced conformational changes in the double bidentate halogen‐bond donors could be exploited to obtain different 1D and 2D networks. All solid‐state studies were accompanied by DFT calculations to predict and rationalize the outcome.
Author: | David BulfieldGND, Elric EngelageORCiDGND, Lucas MancheskiGND, Julian StoesserGND, Stefan M. HuberORCiDGND |
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URN: | urn:nbn:de:hbz:294-75730 |
DOI: | https://doi.org/10.1002/chem.201904322 |
Parent Title (English): | Chemistry |
Subtitle (English): | double two‐point donors and acceptors at work |
Publisher: | Wiley-VCH Verlag |
Place of publication: | Weinheim |
Document Type: | Article |
Language: | English |
Date of Publication (online): | 2020/10/09 |
Date of first Publication: | 2019/10/22 |
Publishing Institution: | Ruhr-Universität Bochum, Universitätsbibliothek |
Tag: | DFT calculations; Supramolecular chemistry; crystal engineering; halogen bonds; molecular recognition |
Volume: | 26 |
Issue: | 7 |
First Page: | 1567 |
Last Page: | 1575 |
Note: | Dieser Beitrag ist auf Grund des DEAL-Wiley-Vertrages frei zugänglich. |
Institutes/Facilities: | Lehrstuhl für Organische Chemie I |
Dewey Decimal Classification: | Naturwissenschaften und Mathematik / Chemie, Kristallographie, Mineralogie |
open_access (DINI-Set): | open_access |
faculties: | Fakultät für Chemie und Biochemie |
Licence (English): | Creative Commons - CC BY-NC 4.0 - Attribution-NonCommercial 4.0 International |