Crystal engineering with multipoint halogen bonding

  • The combination of singly or doubly bidentate halogen‐bond donors with double bidentate acceptors was investigated as a supramolecular synthon in crystal engineering. The crystal topologies obtained feature novel halogen‐bonding motifs like double two‐point recognition and infinite chains or networks based on two‐point interactions. Induced conformational changes in the double bidentate halogen‐bond donors could be exploited to obtain different 1D and 2D networks. All solid‐state studies were accompanied by DFT calculations to predict and rationalize the outcome.

Download full text files

Export metadata

Additional Services

Share in Twitter Search Google Scholar
Metadaten
Author:David BulfieldGND, Elric EngelageORCiDGND, Lucas MancheskiGND, Julian StoesserGND, Stefan M. HuberORCiDGND
URN:urn:nbn:de:hbz:294-75730
DOI:https://doi.org/10.1002/chem.201904322
Parent Title (English):Chemistry
Subtitle (English):double two‐point donors and acceptors at work
Publisher:Wiley-VCH Verlag
Place of publication:Weinheim
Document Type:Article
Language:English
Date of Publication (online):2020/10/09
Date of first Publication:2019/10/22
Publishing Institution:Ruhr-Universität Bochum, Universitätsbibliothek
Tag:DFT calculations; Supramolecular chemistry; crystal engineering; halogen bonds; molecular recognition
Volume:26
Issue:7
First Page:1567
Last Page:1575
Note:
Dieser Beitrag ist auf Grund des DEAL-Wiley-Vertrages frei zugänglich.
Institutes/Facilities:Lehrstuhl für Organische Chemie I
Dewey Decimal Classification:Naturwissenschaften und Mathematik / Chemie, Kristallographie, Mineralogie
open_access (DINI-Set):open_access
faculties:Fakultät für Chemie und Biochemie
Licence (English):License LogoCreative Commons - CC BY-NC 4.0 - Attribution-NonCommercial 4.0 International